Table 4

Summary of microthermometric and Raman spectroscopy data of fluid inclusions from the Puy-les-Vignes deposit.

Fluid inclusions hosted in quartz Fluid inclusions hosted in wolframite


Aqueous-carbonic Lc-w Aqueous-carbonic Lw-c Aqueous Lw Aqueous-carbonic Lw-c
Composition H2O–NaCl–(KCl)–CO2–CH4–N2 H2O–NaCl–(KCl)–CO2–CH4–N2 H2O–NaCl H2O–NaCl–(KCl)–CO2–CH4–N2
Petrography
Phase at room temperature Laq-Lcar-Vcar Laq-V Laq-V Laq-V
Size (μm) 5 to 70 (avg = 21) 10 to 50 (avg = 20) 5 to 15 (avg = 9) 20 to 50 (avg = 30)
Gas/liquid ratio (Rv) 0.10 to 0.70 (avg = 0.38) 0.10 to 0.50 (avg = 0.17) 0.05 to 0.35 (avg = 0.13) 0.30 to 0.60 (avg = 0.45)
Microthermometry n = 189 n = 218 n = 145 n = 25
Tm CO2 (°C) −64.3 to −56.5 (avg = −58.3) −103 to −57.4 (avg = −61.6)
Te (°C) −24.5 to −21.1 (avg = −22.4) −38 to −21.1 (avg = −24.6) −23 to −21.6 (avg = −22.3)
Tm clat (°C) 3.9 to 13.1 (avg = 8.7) 2.9 to 15.2 (avg = 10.8) 11.0 to 14.5 (avg = 12.9)
Tm ice (°C) −10.2 to −1.2 (avg = −6.2) −9.7 to −0.2 (avg = −3.6) −5.5 to −0.2 (avg = −3.0) −5.6 to −3.0 (avg = −4.1)
Th CO2 (°C) −9.7 to 23.3 (avg = 14.1)
Th (°C) 249 to 455 (avg = 337) 246 to 412 (avg = 321) 124 to 391 (avg = 236) 344 to 365 (avg = 353)
Raman spectroscopy n = 55 n = 31
CO2 (mol%) 68.8 to 97.9 (avg = 91.4) 0 to 100 (avg = 62.5)
CH4 (mol%) 0.4 to 11.6 (avg = 2.7) 0 to 86.1 (avg = 29)
N2 (mol%) 0 to 26.2 (avg = 5.9) 0 to 41 (avg = 8.4)
H2S (mol%) 0 to 0.3 (avg = 0.03) 0 to 1.1 (avg = 0.1)
Bulk composition
Salinity (wt.% NaCl eq) 2.20 to 8.10 (avg = 5.26) 0.72 to 5.80 (avg = 2.65) 0.35 to 8.60 (avg = 4.90) 4.96 to 8.68 (avg = 6.60)
Density (g cm−3) 0.36 to 0.92 (avg = 0.67) 0.47 to 0.92 (avg = 0.67) 0.63 to 0.99 (avg = 0.85) 0.66 to 0.73 (avg = 0.69)

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